Pi∝e−Ei/kTcap P sub i ∝ e raised to the negative cap E sub i / k cap T power
is the Boltzmann constant. Essentially, particles are more likely to stay in low-energy states, but as temperature rises, they "explore" higher energy levels. 3. The Partition Function ( Statistical Thermodynamics Fundamentals an
Z=∑e−Ei/kTcap Z equals sum of e raised to the negative cap E sub i / k cap T power Once you calculate Pi∝e−Ei/kTcap P sub i ∝ e raised to
particles, we use "ensembles" (idealized mental collections of systems): Constant energy, volume, and particles ( Canonical: Constant temperature, volume, and particles ( but as temperature rises